Alkanes and alkenes react differently with bromine and potassium permanganate.

Reaction of Alkanes with Bromine:

Alkanes typically do not react with bromine in the absence of light or heat. However, when exposed to light or heat, alkanes can undergo a free radical substitution reaction with bromine, which results in the formation of a bromoalkane. The equation for this reaction is:

CnH2n+2 + Br2 → CnH2n+2Br

Reaction of Alkenes with Bromine:

Alkenes can react with bromine in the absence of light or heat. This reaction is called an electrophilic addition reaction, and it results in the formation of a dibromoalkane. The equation for this reaction is:

CnH2n + Br2 → CnH2nBr2

Reaction of Alkanes with Potassium Permanganate:

Alkanes do not react with potassium permanganate in the absence of heat or an acid catalyst. However, when heated with an acid catalyst, alkanes can undergo an oxidation reaction that results in the formation of carboxylic acids or alcohols. The equation for this reaction is:

CnH2n+2 + KMnO4 + H+ → CnH2n+1COOH or CnH2n+1OH

Reaction of Alkenes with Potassium Permanganate:

Alkenes do not react with potassium permanganate in the absence of heat or an acid catalyst. However, when heated with an acid catalyst, alkenes can undergo an oxidation reaction that results in the formation of carboxylic acids or alcohols. The equation for this reaction is:

CnH2n + KMnO4 + H+ → CnH2n-1COOH or CnH2n-1OH

It’s important to note that the reagents used and the conditions for the reaction can affect the products formed in these reactions.